RISCTOX Database

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4-amino-4,5-dihydro-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5-one, 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one, metribuzin (ISO)@metribuzin@4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one @4-Amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H)-one@Bay 94337 @Triazin-5(4H)-one, 4-amino-6-tert-butyl-3-(methylthio)-@

Identification

Name:
4-amino-4,5-dihydro-6-(1,1-dimethylethyl)-3-methylthio-1,2,4-triazin-5-one, 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one, metribuzin (ISO)@metribuzin@4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one @4-Amino-6-tert-butyl-3-(methylthio)-as-triazin-5(4H)-one@Bay 94337 @Triazin-5(4H)-one, 4-amino-6-tert-butyl-3-(methylthio)-@
Synonyms:
  • METRIBUZIN (ISO)
  • 4-AMINO-6-terc-BUTIL-3-METILTIO-1,2,4-TRIAZIN-5-ONA
CAS:
21087-64-9
EC/EINECS:
244-209-7
Molecular Formula:
C8H14N4OS
International Chemical Safety Card (ICSC):
0516
Uses:
herbicide pesticide

Black list

Substances particularly hazardous to the environment or health

CLASSIFICATION AND LABELLING (Regulation 1272/2008)

Symbols

  • GHS07

    Acute toxicity (oral, dermal, inhalation

  • GHS09

    Hazardous to the aquatic environment

H Phrases

  • H302 : Harmful if swallowed

    Acute Tox. (Cat. 4 *) : Acute toxicity

  • H400 : Very toxic to aquatic life

    Aquatic Acute (Cat. 1) : Hazardous to the aquatic environment

  • H410 : Very toxic to aquatic life with long lasting effects

    Aquatic Chronic (Cat. 1) : Hazardous to the aquatic environment

Labelling
Concentration Labelling
M=10

Specific health risks

As per IARC ?

Substances classified by the International Agency for Research on Cancer (IARC/WHO) according to their evidence of carcinogenicity in humans. Groups range from 1 (proven human carcinogen) to 4 (probably not carcinogenic to humans). The IARC classification is an international reference in occupational and environmental health.

IARC Group
IARC Volume
IARC Notes
List
As per other sources

List generated from dn_risc_sustancias_cancer_otras

Category
Source
List
Endocrine disruptors ?

Substances with endocrine disrupting activity

Disruptor level
NS, UE2, OSF
List
Occupational Exposure Limits (OEL) ?

Daily exposure limit values (VLA-ED) published by the Spanish National Institute of Safety and Health at Work (INSST). They represent the average concentration of a chemical agent in the worker's breathing zone, measured or calculated in a time-weighted manner for an 8-hour daily working period.

OEL Data
List

Environmental regulations

Major accident hazards (Seveso) ?

Hazardous substances listed in Annex I of the Seveso III Directive (Directive 2012/18/EU), transposed in Spain by Royal Decree 840/2015. Their presence in industrial establishments in quantities equal to or above established thresholds triggers obligations to implement major accident risk control measures.

List

Restriction/prohibition regulations

Substances under evaluation. PACT ?

Substances under active regulatory monitoring through ECHA's PACT (Public Activities Coordination Tool). Allows tracking which regulatory authorities are examining a substance and what potential regulatory actions are being considered (restriction, SVHC identification, harmonised classification, etc.).

Member State
Activity
Last update
Scope
List
Authorized Pesticide ?

Active substances approved for use in plant protection products (agricultural pesticides) in the European Union under Regulation (EC) No 1107/2009. Includes herbicides, fungicides, insecticides, acaricides and other crop protection agents with current European-level approval.

Source
Real Decreto 2163/1994
Renewal deadline
Minimum Purity
Uses
List