ETUI – European Trade Union Institute Fundación 1º de Mayo
ISTAS – Institut Sindical de Treball, Ambient i Salut

RISCTOX Database

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Identification

Name:
hydrogen peroxide
Synonyms:
  • AGUA OXIGENADA ...%
  • PEROXIDO DE HIDROGENO
  • AGUA OXIGENADA
  • PEROXIDO DE HIDROGENO, EN DISOLUCION ... %
CAS:
7722-84-1
EC/EINECS:
231-765-0
Molecular Formula:
H2O2
International Chemical Safety Card (ICSC):
0164
Uses:
oxidizer pesticide bleaching agent disinfectant cleaner additive sterilizer

CLASSIFICATION AND LABELLING (Regulation 1272/2008)

Symbols

  • GHS03

    Oxidising gases

  • GHS05

    Corrosive to metals

  • GHS07

    Acute toxicity (oral, dermal, inhalation

Signal word

Danger

H Phrases

  • H271 : May cause fire or explosion; strong oxidizer

    Ox. Liq. (Cat. 1) : Oxidising liquid

  • H332 : Harmful if inhaled

    Acute Tox. (Cat. 4 *) : Acute toxicity

  • H302 : Harmful if swallowed

    Acute Tox. (Cat. 4 *) : Acute toxicity

  • H314 : Causes severe skin burns and eye damage

    Skin Corr. (Cat. 1A) : Skin corrosion/irritation

Notes

  • R.1272-Note B
Labelling
Concentration Labelling
C >= 50 % Xn; R20
C >= 8 % Xn; R22
C >= 70 % C; R35
50 % <= C < 70 % C; R34
35 % <= C < 50 % Xi; R37/38
8 % <= C < 50 % Xi; R41
5 % <= C < 8 % Xi; R36
C >= 50% Footnote O; R8
C >= 70 % R5
C >= 70 %**** Líq. comb., 1; H271
50 % <= C < 70 % **** Líq. comb., 2; H272
*
C >= 70 % Corr. cut., 1A; H314
50 % <= C < 70 % Corr. cut., 1B; H314
35 % <= C < 50 % Irrit. cut., 2; H315
8 % <= C < 50 % Les. oc., 1; H318
5 % <= C < 8 % Irrit. oc., 2; H319
STOT SE 3; H335; C >= 35 %

Specific health risks

Carcinogens (other sources) ?

Substances classified as carcinogens or mutagens Category 3 under the Dangerous Preparations Directive criteria (pre-CLP). Substances with limited evidence or indications of carcinogenicity or mutagenicity.

Category
G-A3
Source
ACGIH
List
According to IARC ?

Substances classified as carcinogens or mutagens Category 2 under the CLP Regulation (GHS), bearing H351 and/or H341 phrases. These are substances suspected of causing cancer or heritable genetic mutations in humans.

IARC Group
Grupo 3
IARC Volume
(VOL. 36, SUPL. 7, VOL. 71; 1999)
IARC Notes
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List
Occupational Exposure Limits (OEL) ?

Daily exposure limit values (VLA-ED) published by the Spanish National Institute of Safety and Health at Work (INSST). They represent the average concentration of a chemical agent in the worker's breathing zone, measured or calculated in a time-weighted manner for an 8-hour daily working period. (https://www.insst.es/valores-limites-de-exposicion)

OEL Data
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List

Specific environmental risks

Hazardous water substances (Germany) ?

Substances classified with chronic aquatic toxicity under the CLP Regulation (H410–H413 phrases, Aquatic Chronic categories 1 to 4). They pose a long-term hazard to aquatic organisms, even at low concentrations and through prolonged exposure.

MMA Classification
1
List

Restriction/prohibition regulations

Major accident hazards (Seveso) ?

Hazardous substances listed in Annex I of the Seveso III Directive (Directive 2012/18/EU), transposed in Spain by Royal Decree 840/2015. Their presence in industrial establishments in quantities equal to or above established thresholds triggers obligations to implement major accident risk control measures.

List
Substances under PACT evaluation ?

Substances under active regulatory monitoring through ECHA's PACT (Public Activities Coordination Tool). Allows tracking which regulatory authorities are examining a substance and what potential regulatory actions are being considered (restriction, SVHC identification, harmonised classification, etc.).

Member State
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Activity
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Last update
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Scope
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List