ETUI – European Trade Union Institute Fundación 1º de Mayo
ISTAS – Institut Sindical de Treball, Ambient i Salut

RISCTOX Database

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Identification

Name:
butanone, ethyl methyl ketone@butanone
Synonyms:
  • ETILMETILCETONA
  • ETIL METIL CETONA
  • METILETIL CETONA
  • METILETILCETONA
  • METIL ETIL CETONA
  • MEK
  • 2-BUTANONA
CAS:
78-93-3
EC/EINECS:
201-159-0
Molecular Formula:
C4H8O
International Chemical Safety Card (ICSC):
0179
Uses:
degreaser solvent cleaner

CLASSIFICATION AND LABELLING (Regulation 1272/2008)

Symbols

  • GHS02

    Flammable gases

  • GHS07

    Acute toxicity (oral, dermal, inhalation

Signal word

Danger

H Phrases

  • H225 : Highly flammable liquid and vapour

    Flam. Liq. (Cat. 2) : Flammable liquid

  • H319 : Causes serious eye irritation

    Eye Irrit. (Cat. 2) : Serious eye damage/eye irritation

  • H336 : May cause drowsiness or dizziness

    STOT SE (Cat. 3) : Specific target organ toxicity - single exposure

  • EUH066

Specific health risks

Neurotoxic substances ?

Substances with neurotoxic effects

Neurotoxic effect

SNC

Level

1

Source

14, 24

List
Occupational Exposure Limits (OEL) ?

Daily exposure limit values (VLA-ED) published by the Spanish National Institute of Safety and Health at Work (INSST). They represent the average concentration of a chemical agent in the worker's breathing zone, measured or calculated in a time-weighted manner for an 8-hour daily working period. (https://www.insst.es/valores-limites-de-exposicion)

OEL Data

VLA-ED

200 ppm

600 mg/m3


VLA-EC

300 ppm

900 mg/m3



List
Biological Exposure Indices (BEI) ?

Biological limit values (VLB) published by the Spanish National Institute of Safety and Health at Work (INSST). Reference values for assessing the risk of chemical agents by measuring them or their metabolites in biological matrices (blood, urine, exhaled air) of exposed workers.

BEI Data

IB: Metiletilcetona en orina

2 mg/l

List

Specific environmental risks

Volatile organic compounds ?

Volatile Organic Compounds (VOCs) regulated by Directive 1999/13/EC on the limitation of VOC emissions from certain activities, and by Royal Decrees 117/2003 and 227/2006. Substances contributing to tropospheric ozone formation that are subject to emission limits in industrial activities.

List

Environmental regulations

LPCIC (EPER)

Priority substances and specific pollutants within the EU water policy framework, established by the Water Framework Directive (2000/60/EC) and the Priority Substances Directive (2008/105/EC and amendments). Substances posing significant risk to European surface waters and subject to Environmental Quality Standards (EQS).

EPER Water

false

EPER Air

true

EPER Soil
—
List
EPER Air ?

Substances from List 2 of Annex III of the IPPC Directive (integrated into the Industrial Emissions Directive 2010/75/EU). Pollutants that may affect surface and groundwater bodies and must be considered in the integrated environmental authorisation of industrial installations.

List

Restriction/prohibition regulations

Substances under CoRAP evaluation ?

Substances included in the Community Rolling Action Plan (CoRAP) of the REACH Regulation. These are substances selected for evaluation by EU Member States due to indications of risk to human health or the environment, with the aim of clarifying whether regulatory action is warranted.

Year
2018
Member State

Sweden

Initial grounds for concern

Suspected Reprotoxic; Wide dispersive use; Consumer use; Exposure of environment; Exposure of workers; High RCR; High (aggregated) tonnage; Potential endocrine disruptor

List
Major accident hazards (Seveso) ?

Hazardous substances listed in Annex I of the Seveso III Directive (Directive 2012/18/EU), transposed in Spain by Royal Decree 840/2015. Their presence in industrial establishments in quantities equal to or above established thresholds triggers obligations to implement major accident risk control measures.

List
Substances under PACT evaluation ?

Substances under active regulatory monitoring through ECHA's PACT (Public Activities Coordination Tool). Allows tracking which regulatory authorities are examining a substance and what potential regulatory actions are being considered (restriction, SVHC identification, harmonised classification, etc.).

Member State
—
Activity
—
Last update
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Scope
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